Beilstein J. Org. Chem.2013,9, 1455–1462, doi:10.3762/bjoc.9.165
are used. Characterization of these palladium complexes strongly supports a mechanistic proposal for the catalytic guanylation of anilines using PdCl2(NCCH3)2 as catalyst that involves the intermediacy of these Pd(II) complexes.
Keywords: coordination chemistry; guanylationreaction; homogeneous
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Graphical Abstract
Scheme 1:
Isolation of trans-dichlorobis(4-iodoanilino-ĸN)palladium(II) and trans-dichlorobis[1,3-diisopropyl...